Sodium piperidine-1-carbodithioate dihydrate

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Sodium piperidine-1-carbodithio­ate dihydrate

The asymmetric unit of the title compound, Na(+)·C(6)H(10)NS(2) (-)·2H(2)O, is composed of a sodium cation, a piperidine-dithio-carbamate anion which exhibits positional disorder, and two lattice water mol-ecules. The atoms of the piperidine ring are divided over two sites with occupancy factors of 0.554 (6) and 0.446 (6). In the crystal, the sodium cation (coordination number of 6) and the pip...

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Phenyl piperidine-1-carboxyl­ate

In the title compound, C(12)H(15)NO(2), the dihedral angle between the benzene ring and the basal plane of the piperidine ring (which is in a chair conformation) is 49.55 (8)°. In the crystal, mol-ecules are linked by C-H⋯O hydrogen bonds and very weak C-H⋯π inter-actions.

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Ammonium piperidine-1-carbodithio­ate

The title compound, NH(4) (+)·C(6)H(10)NS(2) (-), is composed of an ammonium cation and a piperidine-1-carbodithio-ate anion which exhibits positional disorder. The atoms of the ring have a structural disorder and they are divided into two sites, with occupancy factors of 0.584 and 0.426.. In the crystal, the cation and anion are linked by N-H⋯S hydrogen bonds to form an infinite two-dimensiona...

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Piperidine-1-carboximidamide

In the title compound, C(6)H(13)N(3), the C=N and C-N bond lengths in the CN(3) unit are 1.3090 (17), and 1.3640 (17) (C-NH(2)) and 1.3773 (16) Å, indicating double- and single-bond character, respectively. The N-C-N angles are 116.82 (12), 119.08 (11) and 124.09 (11)°, showing a deviation of the CN(3) plane from an ideal trigonal-planar geometry. The piperidine ring is in a chair conformation....

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Piperidine-1-carboxamidinium ethyl carbonate

In the title salt, C6H14N3(+)·C3H5O3(-), the C-N bond lengths in the central CN3 unit of the carboxamidinium cation are 1.3262 (18), 1.3359 (18) and 1.3498 (18) Å, indicating partial double-bond character. The central C atom is bonded to the three N atoms in a nearly ideal trigonal-planar geometry and the positive charge is delocalized in the CN3 plane. The piperidine ring is in a chair conform...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2011

ISSN: 1600-5368

DOI: 10.1107/s1600536811022604